Transition metal clusters are closed polyhedral molecules that have been studied intensively for their relevance in catalysis, surface science and chemical physics. More recently, clusters have been identified as promising optical limiters, required for many technological applications including optical device and eye protection from high power lasers. We have developed high-yielding routes into clusters incorporating very different metals and are exploring their reaction chemistry, electronic and optical properties, and their incorporation into polymer backbones. This has afforded the most metal-rich polymers thus far.
Chi Zhang (Jiangsu University, Zhenjiang, China)
Marek Samoc (Wroclaw, Poland)
- N.T. Lucas, M.G. Humphrey and A.D. Rae, Macromolecules, 2001,34, 6188-6195:
- Mixed-metal cluster chemistry. 16. Syntheses of oligourethanes containing clusters in the backbone
- N.T. Lucas, J.P. Blitz, S. Petrie, R. Stranger, M.G. Humphrey, G.A. Heath and V. Otieno-Alego, J. Am. Chem. Soc., 2002, 124, 5139-5153:
- Mixed-metal cluster chemistry. 19. Crystallographic, spectroscopic, electrochemical, spectroelectrochemical and theoretical studies of systematically varied tetrahedral group 6-iridium clusters
- A.J. Usher, N.T. Lucas, G.T. Dalton, M.D. Randles, L. Viau, M.G. Humphrey, S. Petrie, R. Stranger, A.C. Willis and A.D. Rae, Inorg. Chem., 2006, 45, 10859-10872:
- Mixed-metal cluster chemistry. 29. Core expansion and ligand-driven metal exchange at group 6-iridium clusters
- M.D. Randles, N.T. Lucas, M.P. Cifuentes, M.G. Humphrey, M.K. Smith, A.C. Willis, and M. Samoc, Macromolecules, 2007, 40, 7807-7818:
- Mixed-metal cluster chemistry. 30. Syntheses and optical limiting properties of cluster-containing oligo- and polyurethanes
- C. Zhang, Y. Cao, J. Zhang, S. Meng, T. Matsumoto, Y. Song, J. Ma, Z. Chen, K. Tatsumi, M. G. Humphrey, Adv. Mater., 2008, 20, 1870-1875:
- Modulation of third-order nonlinear optical properties by backbone modification of polymeric pillared-layer heterometallic clusters.
- C. Zhang, T. Matsumoto, M. Samoc, S. Petrie, S. Meng, T. C. Christopher, R. Stranger, J. Zhang, M. G. Humphrey, K. Tatsumi,Angew. Chem. Int. Ed., 2010, 49, 4209 - 4212:
- Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption.