Think that aluminium chemistry is all about the +3 oxidation state? In the Hicks group we think not. This project involves the synthesis and reactivity of a range of aluminium complexes in the rare formal oxidation states +2 and +1.
Small molecules (e.g. CO, CO2 and NO2) are cheap, sustainable, non-fossil-derived starting materials for the synthesis of the fine chemicals that we use in our everyday lives (pharmaceuticals, polymers etc.). However, due to the high thermodynamic stability of these small molecules, they require ‘activation’ before use. This project will involve the synthesis of a series of highly reactive low valent aluminium compounds for the activation of small molecules. The project will involve training in the use of highly reactive, air-sensitive reagents which require handling under strict anaerobic conditions. X-ray crystallography and multinuclear NMR spectroscopy are the common characterisation techniques that will be used on a daily basis.

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