Making high-value metal-organic framework materials from waste plastics
This project repurposes waste PET plastic into precursors for high-value MOFs, aiming to reduce costs and support sustainable production of porous materials for CO₂ capture, catalysis, and gas storage.
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Metal-organic frameworks (MOFs) are a relatively new and exciting class of porous materials comprised of 3D networks of metal sites and organic linkers and are conveniently formed by self-assembly. They are some of the highest surface area materials known, and are promising materials for CO2 sequestration, catalysis, hydrogen storage and gas separations due to their high surface area and versatile compositions and structure. However, the high cost of the chemical precursors for these MOF materials is a major limiting factor for their commercialization and large-scale industrial applications. This project is aimed at using a new technique developed by the group to recycle waste polyethylene terephthalate (PET) - a commodity plastic, ubiquitous in the form of plastic bottles and containers, and a major contributor to urban pollution- into a sustainable source of starting materials for making high-value, functional MOF materials.